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大巴山区土壤中硒、氟的地球化学特征

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  • 中国科学院地理科学与资源研究所, 北京 100101
王五一(1949-),男,研究员,博士生导师。长期从事环境生命元素与与健康方向研究工作。E-mail: wangwy@igsnrr.ac.cn

收稿日期: 2002-08-26

  修回日期: 2002-10-28

  网络出版日期: 2003-04-15

基金资助

国家自然科学基金项目(40171006);中国科学院地理科学与资源研究所创新项目(CXIOGA0205)

The geochemical characteristics of selenium and fluorine in soils of Daba Mountains

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  • Institute of Geographic Sciences and Natural Resources Research, CAS, Beijing 100101, China

Received date: 2002-08-26

  Revised date: 2002-10-28

  Online published: 2003-04-15

摘要

以大巴山区典型土壤为对象,研究了大巴山区土壤中硒、氟等生命元素的含量、分布及影响因素。结果表明:大巴山土壤中硒、氟的背景值高,其含量远高于全国土壤背景值;硒、氟在土壤剖面上的分布存在空间差异,总体趋势是硒在表土层聚集,氟在心土层淀积;土壤中硒、氟的含量受土壤母质的控制,同时,表生地球化学作用、生物作用以及人类活动也深刻影响它们在土壤中的重新分配

本文引用格式

王五一, 李永华, 雒昆利, 杨林生 . 大巴山区土壤中硒、氟的地球化学特征[J]. 地理研究, 2003 , 22(2) : 177 -184 . DOI: 10.11821/yj2003020006

Abstract

Se and F are important life elements closely related to health Toxicity or deficiency diseases in plants, animals and human bodies may arise from the abnormal distribution of Se and F in the natural environment In addition, serious pollution effects caused by rapid industrialization and urbanization also create uneven distribution of Se and F, threatening the health of all living organisms Scientists of related disciplines have, in recent years, faced these issues and been involved in studying such relationships Daba Mountains, one of the most poverty stricken areas of China, is also an area with high occurrence of coal burning fluorosis Moreover, its environmental enrichment of Se has produced new problems concerning potential toxicity effects and threats to human health In this work, typical soil profiles in Daba Mountains are selected as our investigative objects, the concentrations and distributions of Se and F in soils are studied The results are shown as follows: The mean concentrations of Se and F in soils of Daba Mountains are 5 70±13 31 μg/g and 622±434 μg/g, respectively, and those values are far higher than their background values in soils of whole China; distributions of Se and F in soil profiles are not the same In general, Se is enriched in surface soil layer, whereas F is enriched in subsoil layer;Se and F concentrations in soils are mainly governed by their concentrations in soil parent The correlation between the two variables can be expressed as Y Se =1 266X Se -0 547(r=0 995, P<0 01), Y F =0 340X F +258 25(r=0 762, P<0 05), respectively, where Y is the Se or F concentrations in soil, and X is the Se or F concentrations in the soil parent Otherwise, environmental geochemical processes, biologic processes and human actions can also profoundly impact the concentrations and redistributions of Se and F in soils

参考文献


[1] 梅紫青.我国发现的两个硒区综述.中国地方病学杂志,1985,4:379~385.
[2] 聂树人.陕西自然地理.西安:西安人民出版社,1981.
[3] 陈宝群,李俊岭,王亚平,等.秦巴山地石煤产区燃煤型氟中毒流行现状调查分析.中国地方病学杂志,1997,16(5):270~273.
[4] 雒昆利,陈德岭,葛岭梅.陕西古生界黑色岩系及煤系共生伴生矿产.西安:西北大学出版社,1994. 36~41.
[5] 雒昆利,潘云唐,王五一.南秦岭早古生代地层含硒量及硒的分布规律.地质论评,2001,47(2):211~217.
[6] 白广禄.陕西省地方性氟中毒与地理因素的关系.中国地方病防治杂志,1997,16(1):57~59.
[7] 李永华,王五一,侯少范.我国地方性氟中毒病区环境氟的安全阈值.环境科学,2002,23(4):118~122.
[8] 程静毅,梅紫青.陕西紫阳县硒中毒区初步调查报告.陕西农业科学,1980,6:17~19.
[9] 冯新斌,洪冰,倪建宇.煤中部分潜在毒害元素在表生条件下的化学活动性.环境科学学报,1999,19(4):433~436.
[10] 卢衍豪.中国的寒武系.北京:科学出版社,1962.
[11] 黄振辉.关于秦岭地质的研究.科学通报,1960,8:255~256.
[12] 李日邦,谭见安,王丽珍.我国不同地理条件下耕作土中的氟及其与地方性氟中毒的关系1地理研究,1985,4(1):30~40.
[13] 侯少范,李德珠,王丽珍.我国土壤中结合态硒的含量和分布规律.地理研究,1990,9(4):17~25.
[14] 赵成义,任景华,薛澄泽.紫阳富硒区土壤中的硒.土壤学报,1993,30(3):253~259.
[15] 李继云,任尚学,陈代中,等.陕西省环境中的硒与大骨节病关系的研究.环境科学学报,1982,2(2):91~101.
[16] 侯少范,王五一.微量硒的测定方法简介.分析化学,1980,8(2):183~187.
[17] Mcquaker N R,Gurney M1 Determination of total fluoride in soil and vegetation using an alkali fusion2selective ion electrode technique. Anal Chem,1977,49(1):47~53.
[18] 王云,魏复盛.土壤环境元素化学.北京:中国环境科学出版社,1993.
[19] Arnesen A K M. Effect of fluoride pollution on pH and solubility of Al,Fe,Ca,Mg,K and organic matter in soil from Ardal.Water Air Soil Pollu,1998,103:375~388.
[20] Polomski J,Flühler H,Blaser P. Accumulation of airborne fluoride in soils1 J.Environ. Qual,1982,11(3):457~461.
[21] Swaine D J. Trace Elements in Coal. London:Butterworths,1990.
[22] 中国科学院贵阳地球化学研究所1简明地球化学手册.北京:科学出版社,1977.
[23] 何振立,周启星,谢正苗.污染及有益元素的土壤化学平衡.北京:中国环境科学出版社,1998. 307~310.

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